A Fragment of the Unique Atoms in [Co(diNOsar)]3+


Viewing tools:
Which has been replaced by D since we are in D2O
Consistent with our Figures
Top View, Like a Newman Projection

For consistency, we will label the following atoms


    • Your Mission:
    1. Assign the Y proton as Hc or Hd
      For consistency over the class label the proton with similar interactions to both Ha and to Hb as Hc
      and the proton that has one weaker and one stronger interaction (to Ha and Hb) as the Hd proton

    2. Assign the Z proton as Hc or Hd
    3. Have your TA or Instructor check your final labeling scheme.

    4. Finally:
      Using the HETCOR, COSY and NOESY for your Co(diNOsar)Br3 product
      and the HETCOR and COSY for d12-Co(diNOsar)Br3

      Assign all peaks on the 1D spectra as arising from C1, C2, Ha, Hb, Hc, or Hd and then all cross peaks in the 2D NMR spectra as arising from pairs of nuclei using this same numbering/lettering scheme


    Reference: CCDC Structure HARBAD; R.J. Geve, L.M. Englehardt, J. M. Harrowfield
    A.M. Sargenson, A. H. White Aust. J. Chem. Vol 46, 1993, p. 1485

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