G. Mechanisms that can Racemize Λ and Δ Metal Tris Chelates
Non-dissociative Mechanisms: b. The Rây-Dutt Mechanism for GaL3 (L = mda)


Λ-GaL3
Calc C2v TS for the Rây-Dutt


Viewing the Rây-Dutt Mechanism
  2. Compare to Λ
  3. Compare to Δ
Test each isomer before and after one Rây-Dutt:

Δ-GaL3







State whether facial and meridional isomers can, cannot or must be interchanged by a Rây-Dutt Twisting motion
For Information on our GaL3 Complex
and on our Computational Model
Return to Index

Resources developed by Marion E. Cass, Carleton College and updated in 2014. Computations and content done in consultation with Henry S. Rzepa, Imperial College, London