X-ray Structures of [NiII(TPT)]2+, [FeII(TPT)]2+ and [ZnII(TPT)]2+


[NIII2+
(1,4,7-tris(Pyrazol-3-ylmethyl)-1,4,7-triazacyclononane)-nickel(II) di-cation
Note: two perchlorate anions have been removed for clarity of viewing

Zn(II) d10



CCDC Ref: YIRMAN
M.Di Vaira, F.Mani, P.Stoppioni, J.Chem.Soc.,Dalton Trans. , p 3739, 1994 R=5.9
[FeII(TPT)]2+
1,4,7-tris(Pyrazol-3-yl-methyl)-1,4,7-triazacyclononane-iron(II) dication
Note: two counterions hav been removed for clarity of viewing

Fe(II) d6




CCDC Ref: RUKLOY
M.Di Vaira, F.Mani, P.Stoppioni, J.Chem.Soc.,Dalton Trans. , p 1375, 1997 R= 3.6
[ZnII(TPT)]2+
1,4,7-tris(Pyrazol-3-yl-methyl)-1,4,7-triazacyclononane-zinc(II) dication
Note: two perchlorate counterions hav been removed for clarity of viewing

Zn(II) d10




CCDC Ref: YIRMER
M.Di Vaira, F.Mani, P.Stoppioni, J.Chem.Soc.,Dalton Trans. , p 3739, 1994

Resources developed by Marion E. Cass, Carleton College 2016